I'm fairly certain this is Mt. Ouray and Chipeta Mtn.
That's not the Spanish Peaks?
Looks like Ouray and Chipeta to me. If you were pointing just east of due south, then maybe, but I'll bet you were pointed west. I'm looking at the way the shadows lie, and at this time of day I think you're looking west. Plus, the eastern bowl on Ouray, and the Devil's Armchair, are pretty easy to pick out, even from this distance. I can't check while I type this, but I'll bet the Ouray page would confirm this. (Is there a Ouray page? I don't remember! Must go check...)